zAdvanced coal liquefaction process, mild reaction and operating conditions: Operating pressure 18MPa Operating temperature 445～455℃ zNew and highefficiency coal liquefaction catalyst zThe optimized integration of advanced and mature unit processes and technologies has reduced project risks and enhanced the operation reliability and economics.
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coal liquefaction, any process of turning coal into liquid products resembling crude oil. The two procedures that have been most extensively evaluated are carbonization—heating coal in the absence of air—and hydrogenation—causing coal to react with hydrogen at high pressures, usually in the presence of a catalyst.
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Other articles where process is discussed: coal utilization: The FischerTropsch process: .1950s in South Africa (the process) and now supplies as much as onethird of that country's liquid fuels. ... coal liquefaction process. Learn about this topic in these articles: coal processing. In coal utilization: The FischerTropsch ...
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The FischerTropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
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•Brown Coal Liquefaction (BCL) Process NEDO •Amoco CC TSL Process •Supercritical Gas Extraction (SGE) Process British Coal •MITI Mark I and Mark II CoProcessing •Cherry P Process Osaka Gas Co. •Solvolysis CoProcessing Mitsubishi •Mobil CoProcessing
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The direct coal liquefaction process. usually produces a coal liquefaction residue (CLR) of about 30%. of its coal feed (Xu et al., 2014), and there is more than 80%. organic matter in the CLR ...
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The growing demand for petroleum, accompanied by the declining petroleum reserves and the concerns over energy security, has intensified the interest in direct coal liquefaction (DCL), particularly in countries such as China which is rich in coal resources, but short of petroleum. In addition to a general introduction on the mechanisms and processes of DCL, this paper overviews some recent ...
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Indirect liquefaction requires an intermediate gasification of the solid coal to form a synthesis gas, which is then converted to the liquid product. This process results in the complete dismantling of the coal structure. direct liquefaction, coal is exposed directly to hydrogen at high temperatures (450C) and high pressures (kPa ...
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Liquefaction. In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a nonliquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction ...
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This COconversion process generates CO 2, which is captured before it is released via an adsorption process at a purity as high as 90%. The other route is the power and steam consumption for ICLs. The generation of power and steam via coal combustion leads to carbon emissions with CO 2 concentrations in the range of 10~20% in the exhaust gas.
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Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
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Even though the process is currently not in use, it has contributed immensely to the development of catalytic coal liquefaction technology. The process involves the catalytic conversion of coal (slurried with heavy oil) in the presence of hydrogen and an iron oxide catalyst, at 450°C500°C and 200690 bars (197681 atm, or 2069 MPa).
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article{osti_, title = {Novel use of residue from direct coal liquefaction process}, author = {Yang, Jianli and Wang, Zhaixia and Liu, Zhenyu and Zhang, Yuzhen}, abstractNote = {Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of ...
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ash and sulphur content than the original coal. The SRCII process, however, was to produce distillate products; the distinguishing characteristic of the process was the recycle of vacuum bottoms. Two other direct coal liquefaction processes were under development in the USA at the same time: the Exxon Donor Solvent (EDS) process and the HCoal ...
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The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significance for improving the oil yield of the direct liquefaction process and reducing the amount of pollution emitted from this oilcontaining organic solid waste. In ...
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Direct coal liquefaction involves contacting coal directly with a catalyst at elevated temperatures and pressures with added hydrogen (H 2 ), in the presence of a solvent to form a raw liquid product which is further refined into product liquid fuels.
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4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
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Coal liquefaction residue (CLR) is usually categorized as hazardous waste, which is inevitably generated during the coalliquefaction process. Studies show that CLR has a high calorific value and can be used to decrease coal consumption during the cofiring process. In this regard, field tests were carried out to study the emission and ...
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It was reported that the four major operating coal liquefaction pilot plants in the US all experienced problems including severe equipment The commercial Shenhua plant will be a significant step in determining the viability of the direct liquefaction process route. Different from the two indirect routes, the
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article{osti_, title = {Catalyst withdrawal and addition in a coal liquefaction process}, author = {Simone, A A and Ogren, D F}, abstractNote = {The catalyst is withdrawn from a coal hydroliquefaction reactor while it is maintained on stream by withdrawing a portion of the catalyst, in a separate stream, dispersed in product from the liquefaction zone, with such withdrawn stream being ...
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We have launched ISKG for indirect coal liquefaction process, its oriented applications are of great significance in optimizing HAZOP, strengthening industrial safety and popularizing safety prevention awareness. Section 2 is the related work, which mainly reviews HAZOP and KG. Section 3 is the method, we elaborate the development process of ...
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Figure (A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
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Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA ...
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[1] The indirect route is composed of 2 steps: First, coal is gasified with steam and oxygen to produce a synthesis gas (syngas), which is then cleaned to rid of dust, tar, and acid gases.
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A process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid ...
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H5 Significant fluctuations in the light oil yield obtained from laboratory and pilot scale models of heavy oil upgrading. coal/oil coprocessing and direct coal liquefaction processes. arising ...
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Indirect liquefaction process coal is liquefied through the FischerTropsch (FTS) process. The FTS process uses synthesis gas from the gasification process and converts it into liquidous hydrocarbons and associating oxygenated compounds using different catalysts from Group VIII.
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The 150t/day NEDOL coal liquefaction pilot plant (PP) has validated the superior technical features with a highly active liquefaction catalyst and hydrogen donor solvent. The operation runs without any serious trouble and was successfully executed from March 1997 to September 1998. The results were integrated as a "technical package" and the RD is transferred to a commercializing phase.
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In the process of liquefaction, its specific heat varies significantly over temperature, depending on the pressure and composition. Unconventional gas sources are often quite different in composition from conventional gas. For example, coalbed methane and shale gas are both poor gases with high methane content.
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