It can convert biomass into fuel gas, liquid oil, and solid coal efficiently in the absence of oxygen [86,87], which occurs at relatively low temperatures (between 350 and 700 °C). This process involves the heating and drying of a biomass particle, as well as the release of volatiles.
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CoaltoLiquids. CoaltoLiquids (CTL) is a process of converting coal to fuels such as diesel or gas. For diesel, the process involves first building a plant to convert coal to gas and then another plant to covert the gas to a liquid. The resultant liquid fuel is known as synthetic fuel or synfuel. Synfuels are used as an alternative to oil ...
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4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur).
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The coaltoliquids (CTL) technique is a chemical process by which solid coal is converted into ... Emissions of pollutants from raw material processing in the CTL process. In the conversion of coal to liquid hydrocarbon, many kinds of raw materials are consumed, including coal, freshwater, chemical reagents and industrial chemicals, and ...
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Solid hydrocarbons Cleanly converting coal, petroleum coke and biomass into highvalue products and power. Air Products' gasification process converts coal, petcoke and biomass into highvalue products. Demand for coal is increasing because of the world's growing appetite for energy. However, depletion of the highestquality deposits and ...
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obtained from gasification of coal to hydrocarbon liquids. Because the coal is first gasified before conversion to liquid fuels, the FischerTropsch (FT) process for CTL is known as a type of indirect coal liquefaction (ICL). ICL is a completely different approach from DCL for providing liquid fuels from coal. ICL processes first convert ...
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An example of this process is CO2Binding Organic Liquids ... PNNL leads the Core Technology Program for DOE's Solid State Energy Conversion Alliance (SECA) and is developing advanced materials with better fuel cell performance and affordability. ... Researchers also are developing ways to convert coal and other hydrocarbons into a synthetic ...
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HTP was originally invented by the German Nobel laureate Friedrich Bergius for the drying of solid hydrocarbon fuels, also known as wet torrefaction [12, 13] (WT)/hydrothermal dewatering (HTD) [19], which can remove the moisture of biomass in liquid form (coal's temperature = 160350 °C/biomass's temperature = 160250 °C, steam pressure ...
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a gasification plant for converting solid or liquid hydrocarbon fuels into synthesis gas (syngas) 3. a syngas gas cleanup system and. 4. ... of mineral matter suitability are supported by laboratory and technical scale measurements of specific aspects of the coal conversion process.
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The biomass to liquids (BTL) route refers, similar to coal to liquids (CTL) or gas to liquids (GTL) technologies, to biomass conversion into liquid hydrocarbon fuels by the integration of two different processes: biomass gasification to syngas (H 2 /CO) and subsequent FischerTropsch synthesis (FTS) to hydrocarbon fuels.
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The key to the catalytic process is the construction of a highly efficient tandem catalyst PtMo2C/C + Ru/C, which can directly convert CO and H2O in aqueous phase to liquid hydrocarbons with a ...
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Taking the importance of Pakistan's dire need for energy breakthrough, in this paper, we explore how the country's vast estimated reserves of 175 billion tons of Thar coal is a useful source for the clean and efficient production of good quality liquid fuel. Coal to liquid (CTL) technology has gathered increasing attention among many countries with a sufficient volume of coal reserves, and ...
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The diversification of coal for its sustainable utilization in producing liquid transportation fuel is inevitable in countries with huge coal reserves. Gasification has been contemplated as one of the most promising thermochemical routes to convert coal into highquality syngas, which can be utilized to produce liquid hydrocarbons through catalytic FischerTropsch (FT) synthesis. Liquid ...
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The primary process for FT is the Synthol Process; the schematic is shown in Figure The synthesis gas goes into the reactor at MPa of pressure and 315330°C. The product leaves the reactor where the catalyst is recovered, oils are removed by a hydrocarbon scrubber, and the tail gas recovered.
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However, coal and petroleum fuels produce detrimental gases such as carbon dioxide (CO 2), NO x which results in ... The advanced process to convert solid biomass into gas such as H 2 is the steam gasification ... Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels. Energy Environ Sci 4:8399. Google ...
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A process for converting coals to principally hydrocarbon gases, by intimately contacting coals such as lignite coal with a reagent,, alkali metal polysulfides or alkali metal hydrosulfide, in the presence of steam, or a combination of steam and hydrogen, at temperatures between 65 to 450/sup 0/C. Liquid and gaseous hydrocarbons of preselected compositions may be produced; as it is well ...
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216 Coal to Liquid Fuels *ZEESHAN NAWAZ 1, S HAHID NAVEED2, RAO SHAKIL AHMED1, S AAD NAWAZ3 ABSTRACT The processes to convert coal to liquid hydrocarbons that are intended to be sold as an ...
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FischerTropsch (FT) synthesis is a heterogeneous catalytic process that converts biomassderived syngas (mixture of CO and H 2) to synthetic liquid fuels and valuable chemicals. FT synthesis has received renewed interest in recent years due to the necessity to decrease global dependency on fossil fuels. FT synthesis is a promising technology ...
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The required water consumption is in the region of 1m 3 (1 ton) per each barrel of fuel production [77] and the coal (bituminous) consumption is between to ton per barrel, according to ...
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The process which converts solid coal into liquid hydrocarbon fuel is known as coal liquifaction. The liquefaction converts solid coal directly into liquid form with no intermediate step. Suggest Corrections. 0.
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A singlestage process attempts to convert coal to liquids in a single reaction stage. Such process may include an integrated online hydrotreating reactor to upgrade the distillates, as shown in Figure 1. Technology developers included: HCoal (HRI, USA) Exxon donor solvent (Exxon, USA) SRC1 and II (Gulf Oil, USA) Conoco zinc chloride (Conoco ...
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We claim: 1. A continuous two reactor stage coal conversion process for catalytic hydrogenation of coal particles and subsequent liquefaction thereof for producing coalderived hydrocarbon liquid and gas products, said process comprising: (a) mixing solid coal particles having particle size ranging from about 20 mesh to about 400 mesh ( Sieve Series) with hydrocarbon liquid solvent in a ...
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The indirect route is composed of 2 steps: First, coal is gasified with steam and oxygen to produce a synthesis gas (syngas), which is then cleaned to rid of dust, tar, and acid gases. The second step reacts the synthesis gas with a catalyst in the FischerTropsch process, which converts the syngas into a range of hydrocarbon fuels such as ...
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FTS is one of the most important synthetic processes. This process, which provides an effective gas to liquid technology, produces a broad range of hydrocarbon products, which are converted to synthetic lubrication oil and synthetic fuel in subsequent refining process, mainly from coal, natural gas resources or biomass.
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The Synfuels CTL refinery in Secunda uses an alkene oligomerization process based on solid phosphoric acid (SPA) catalysis to convert most of the light alkene HTFT product into liquid fuels . ... Certainly coal conversion to hydrocarbon liquids and electricity is now economically attractive from a cash cost viewpoint. However, large ...
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The influence of high ash content in the feed coal may partially be reduced by selecting an appropriate coal conversion process, its configuration and solidliquid separation to be used in the process (2). However, the most radical approach is to reduce ash content in the coal prior to feeding it into the conversion plant using coal ...
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For the most highly developed processes, coal conversion can be as high as 90% on a mineral ash free basis, with a C 5+ distillate yield up to 75% and hydrogen consumption of 57%wt. When an external catalyst is used, it is typically some combination of cobalt, nickel, and molybdenum on a solid acid support such as silicaalumina [].DCL process concepts have been based on a variety of ...
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