Naphthalene was first isolated from coal tar in 1819 by Alexander Garden; it represents about 10% of this complex mixture of aromatics. The industrial importance of naphthalene dates from the latter half of the last century, owing mainly to the ease with which it can be converted into sulfonic acids and thence also to the naphthols, for use as dyestuffs intermediates.
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It processes the naphthalene fraction from the rectification of coal tar so as to produce naphthalene of grade A and type II according to Technical Specifications TU 14797. Until November 2020, the naphthalene was produced at MMK by solidification of the naphthalene fraction and subsequent mechanical separation of the naphthalene crystals ...
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Coal tar is an important raw material for the production of valuable aromatic compounds [].It has more than 500 components, most of which are aromatic hydrocarbons, including benzene, toluene, xylene, anthracene, naphthalene, and phenanthrene [4, 5].These are precursors for the synthesis of products such as dyes, drugs, explosives, scents, preservatives, synthetic tars, paints, and pigments.
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The organic chemistry industry is based on organic compounds derived from coal, petroleum and gas. Coal tars derived from the carbonisation process are complex mixtures, of which the polycyclic aromatic hydrocarbons (PAH's) are the main component. One of the most important PAH's is naphthalene, which represents between 10 to 12% of the recent years, new applications for industrial ...
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Coal tar naphthalene oil fraction (CTNOF) is typically obtained as a byproduct of the coking process in steel production. When coal is subjected to high temperatures in the absence of air (coking), it undergoes thermal decomposition, yielding various byproducts including coal tar [].This tar can be further processed to extract different fractions, one of which is naphthalene oil [2, 3].
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sumer products. Coal tars are used primarily for the production of refined chemicals and coaltar products, such as creosote, coaltar pitch, and crude naphthalene and anthracene oils from the distillation of crude coal tar. Coal tar has been used as a fuel in openhearth furnaces and blast furnaces in the steel industry, as a binder and filler in
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Report No. COAL TAR CHEMICALS JAMES J. L. MA December 1976 A private report by the a PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE MENLO PARK, CALIFORNIA
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It is a thin, colourless, highly flammable liquid with a characteristic smell. It is a good motor fuel solvent as well as being a feedstock for other benzene derivatives used in dye, insecticides and plastics production. At a later stage in the distillation process, a heavy coal tar solvent naphtha and a naphthalene fraction are produced.
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Coal tar ( ) and coal tar pitch ( ) are the byproducts of the hightemperature treatment of coal to make coke or natural gas. These chemical products usually are thick, black or dark brown liquids or semisolids with a naphthalenelike odor. Coal tar also has a sharp, burning taste.
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HYSYS software indicates high technological flexibility of the process and the production of naphthalene from coal tar that matches the quality of the naphthalene derived from petroleum. The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %.
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Odour: Peculiar, naphthalenelike (Singh, Goyal and Kaur, 2015) ... PROCESS DESCRIPTION Coal Tar ... 2019. Coal Tar Production Processes and Potential of PAHs Release into the Environment. [online ...
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Coal tar is a hazardous and toxic waste, a byproduct of coal gasification processes. Coal tar is a waste produced in industrial fields such as steel, power plant, and the cement industry. As a ...
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Naphthalene is an important component of high temperature coal tar and its content can reach more than 10%. Catalytic polycondensation of naphthalene is an effective way to prepare mesophase pitch and functional carbon materials. ... which may provide valuable hints for exploring the production process of mesophase naphthalene pitch. Declare of ...
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This research presents the first demonstration of substantial microbial degradation and depletion of naphthalene from coal tar, a multicomponent, aromatic, dense nonaqueous phase liquid (NAPL). The rates and extents of microbial degradation of naphthalene from coal tar and from a twocomponent NAPL simpler in composition than coal tar were evaluated in gently mixed, NAPL−water batch systems ...
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Most naphthalene is derived from coal tar. From the 1960s until the 1990s, significant amounts of naphthalene were also produced from heavy petroleum fractions during petroleum refining, but today petroleumderived naphthalene represents only a minor component of naphthalene production. Naphthalene is the most abundant single component of coal tar.
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The naphthalene samples studied in this work were produced by the chemical industry. Fig. 1 shows a process for the production of naphthalene with different degrees of purity. The refined naphthalene came from the catalytic hydrogenation process, (NAFR) (% purity); the industrial naphthalene from a series of distillations (NAFD) (% purity) and the crystallised naphthalene (NAFC) (99 ...
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Naphthalene (also known as naphthalin, naphthaline, moth ball, tar camphor, white tar, or albocarbon), is a crystalline, aromatic, white, solid hydrocarbon, best known as the primary ingredient of is volatile, forming a flammable vapor. Each molecule of this substance consists of two fused benzene rings. As its most abundant single component, it is obtained from coal tar ...
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Introduction. The carbonization of coal to produce metallurgical coke in slottype recovery ovens is the main source of coal tar production, with this coal conversion process constituting the second largest application of coal. Coal tar production is not a primary process target: the main target in the process is the production of metallurgical ...
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The Process Intensification for Syngas Hydrogen key technology area addresses control of chemical reactions in increasingly modular and intrinsically efficient reactors, allowing for streamlined processes with wellcoordinated unit operations, and with a focus on gasification of biomass and carbonaceous wastes into syngas, s.
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But nowadays Bitumen has replaced coal tar to serve this purpose. Naphthalene balls used as moth repellent in the storage areas are the derivatives of coal tar. ... The production process is distinct, both physically and chemically, from that used to create a range of gaseous fuels known variously as manufactured gas, syngas, hygas, Dowson gas ...
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% of the naphthalene in the coal tar; % of the naphthalene fraction is lost with the press runoff. 3. The market is limited because of the minimum product range: only liquid naphthalene can be shipped to the customer. (In April 2012, Rostekhnadzor banned the shipment of pressed naphthalene in railroad cars for lack of mechanization.
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To trace the behavior of naphthalene in the pyrolysis of coal tar, the pyrolysis of coal tar containing 14Clabeled naphthalene was carried out at 800−950 °C for 40−50 s. It was found that naphthalene has significant pyrolysis reactivity. The distributions of the radioactivities in compounds with 3−5 rings were,, and % at 800, 900, and 950 °C for 50 s, respectively ...
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Coal tar. María Antonia Diez, Roberto Garcia, in New Trends in Coal Conversion, 2019. Concluding remarks. With coal tar as a byproduct from cokemaking, coal tar availability will continue to depend on the consumption of coke in the blast furnace for iron and steel production. Thus, the conditions of coke production in recovery coke ovens will play a decisive role in determining ...
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At the moment, most of the aluminum smelters utilize coal tar pitch as binder in their prebaked carbon anode (and graphitized carbon cathode) production processes. Hence, the prediction of the thermodynamic properties of PAHs present in coal tar pitch aimed at phase behavior description of coal tar pitch during heat treatment will be the main ...
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The coal tar evaluation process of its constituent components is carried out by distillation, with a high level of naphthalene purity achieved up to 96%. The coal tar distillation process normally ...
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These advantages of the hydrorefining process have attracted the attention of numerous investigators. A laboratory study has been made of the effects of temperature, partial hydrogen pressure, and space velocity on the amounts of thionapthen and tetralin in the hydroraffinate made by the catalytic hydrorefining of coaltar naphthalene.
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The naphthalene content in the commercial product derived from coal tar by the proposed method is wt %. The yield of naphthalene is wt %. The energy consumption in the basic threecolumn system is Gcal/t of commercial naphthalene (of purity wt %). If heat is recycled in the threecolumn system, the energy consumption is ...
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The study describes the effect of silicon carbide (SiC) nanopowder on the process of coal tar pitch thermal decomposition during heat treatment to a temperature of 2000 ° influence of nanosized SiC powder on the pyrolysis mechanism of carbonisation product yield, as well as structural and microstructural parameters of carbon obtained via carbonisation and further heating up to 2000 °C ...
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An online condensation system was designed to separate coal tar during cooling process. ... The typical contents of most common specialties in different fractions for coal tar are Light oil, Phenol oil, Naphthalene oil, washing oil, anthracene oil. ... The production yield of total tar was about %, %, % and % for 500, 600, 700 ...
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